:

(), (, , , ), PDF-2, , .

, . , , . . ³ 0,03%.

, , ( ) . (a1- a2 ) :

, (1)

I(hkl) hkl; ds ; x, y .

 

, -. -, ( ) (. 1). (. 2) (. 3).

 

. 1 650 (Cu,Zn)

(, , ) ( - , ). - .

. 2 650 (Cu,Zn)

. 3 650 (Cu,Zn)

:

:   :  3. Cu85Zn15 ox. 650C 480 min  

  :  Cu
   :  -.034     

----------------------------------------------------------------------------------
      I    2Theta      d              ZnO                        CuO (tenorite)      
----------------------------------------------------------------------------------
    11.8   31.792   2.8152  :  17.9  2.8132  0   1   0 :        ......            
     6.5   32.556   2.7507  :        ......            :   6.3  2.7485  1   0   1 
    10.7   34.458   2.6030  :  12.7  2.6032  0   0   2 :        ......            
    83.8   35.551   2.5253  :        ......            :  83.8  2.5222 -1   1   1 
    32.9   36.326   2.4732  :  32.9  2.4750  0   1   1 :        ......            
   100.0   38.751   2.3237  :        ......            :  79.8  2.3203  1   1   1 
     3.6   42.340   2.1345  :        ......            :        ......            
     3.3   43.309   2.0889  :        ......            :        ......            
     1.7   46.331   1.9593  :        ......            :   2.4  1.9604 -1   2   1 
     5.2   47.572   1.9110  :   6.5  1.9107  0   1   2 :        ......            
    26.1   48.761   1.8672  :        ......            :  22.1  1.8670 -2   2   0 
     2.0   50.402   1.8101  :        ......            :        ......            
     1.8   51.332   1.7795  :        ......            :   1.6  1.7753  1   2   1 
----------------------------------------------------------------------------------

----------------------------------------------------------------------------------
      I   2Theta      d                Cu                         Cu2O                
----------------------------------------------------------------------------------
    11.8   31.792   2.8152  :        ......            :        ......            
     6.5   32.556   2.7507  :        ......            :        ......            
    10.7   34.458   2.6030  :        ......            :        ......            
    83.8   35.551   2.5253  :        ......            :        ......            
    32.9   36.326   2.4732  :        ......            :   9.8  2.4654  1   1   1 
   100.0   38.751   2.3237  :        ......            :        ......            
     3.6   42.340   2.1345  :        ......            :   3.6  2.1351  2   0   0 
     3.3   43.309   2.0889  :   3.3  2.0897  1   1   1 :        ......            
     1.7   46.331   1.9593  :        ......            :        ......            
     5.2   47.572   1.9110  :        ......            :        ......            
    26.1   48.761   1.8672  :        ......            :        ......            
     2.0   50.402   1.8101  :   1.4  1.8097  0   0   2 :        ......            
     1.8   51.332   1.7795  :        ......            :        ......            
----------------------------------------------------------------------------------

 ZnO   (P63mc   ): a =    3.2484(  16)  b =    3.2484(  16)  c =    5.2063(  24) 
 CuO   (B2/b    ): a =    4.6828(  55)  b =    5.1296(  25)  c =    3.4205(  13) 
 Cu    (Fm3m    ): a =    3.6194(   5)  b =    3.6194(   5)  c =    3.6194(   5) 
 Cu2O  (Pm3m    ): a =    4.2703(   3)  b =    4.2703(   3)  c =    4.2703(   3)